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Well, my guess, after further examination about 5 minutes ago, it's either water condensation (which I doubt considering its ~60-65*F here and it still squealed at startup) or it's loose. I checked and the belt looks brand spanking new - the labeling around the belt giving the brand name (I think) and a model number has no wear or fade at all. This time I got under the car and felt all around the belt as much as I could between the pulleys and there is no smoothness. I played around a bit with the belt, tugging it and pulling it side to side. It seems to stay well, but it isn't death crunching tight.
I guess the first thing I'm going to try is to tighten the belt a little bit. Looking at it, the easiest way seems to be moving the alternator more towards the back of the car. There is an adjustment bracket right above the alternator with a bolt in it. Can I loosen that bolt, move the alternator back as much as possible, and tighten it back up? This in theory would tighten the belt, I'm not sure if it will stop the squeals, but could it hurt anything?
Otherwise I'll resort to baby powder, as Ben suggested. I'm assuming to do this just powder up the belt, particularly on the inner part of the belt that actually touches the pulleys?
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